DRAGNET FT TERMITICIDE / INSECTICIDE
002 01/09/01 DRAGNET FT TERMITICIDE / INSECTICIDE
PRODUCT NAME: DRAGNET FT TERMITICIDE / INSECTICIDE
MSDS NUMBER: FM900004
EFFECTIVE DATE: 8/13/1998
SUPERSEDES: 4/12/1994
ISSUED BY: 008418
This document has been prepared to meet the requirements of the U.S. OSHA
Hazard Communication Standard, 29 CFR 1910.1200; the EC directive, 91/155/EEC
and other regulatory requirements. The information contained herein is for the
concentrate as packaged, unless otherwise noted.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: DRAGNET FT TERMITICIDE/INSECTICIDE
PRODUCT CODE: 1223
ACTIVE INGREDIENT: Permethrin
CHEMICAL FAMILY: Pyrethroid Pesticide
MOLECULAR FORMULA: C21H20Cl2O3 (permethrin)
SYNONYMS: FMC 33297; (3-Phenoxyphenyl)methyl(+/-) cis-trans-3-(2,2-
dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate; IUPAC: 3-phenoxybenzyl
(1RS)-cis-trans-3-(2,2-dichlorovinyl)-2,2- dimethylcyclopropanecarboxylate
MANUFACTURER
FMC CORPORATION
Agricultural Products Group
1735 Market Street
Philadelphia, PA 19103 USA
General Information: 800-321-1362
Emergency Telephone Numbers:
Emergency Phone (FMC) 800-331-3148 (U.S.A. & Canada)
Emergency Phone (FMC) 716-735-3765 (Reverse Charges)
CHEMTREC (800) 424-9300 (U.S.A. & Canada)
(202) 483-7616 (All other countries)
2. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name CAS # Wt.% PEL/TLV EC No. EC Class
Permethrin 52645-53-1 36.8 None 613-058-00-2 R22
Stoddard Solvent 8052-41-3 <12.9 100 ppm None None
Surfactant Blend 0000-00-0 <8.5 None None None
1,2,4-trimethylbenzene
95-63-6 <0.5 25 ppm None None
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS: - Amber liquid with a faint, mild petroleum odor.
- Moderately combustible. May support combustion if heated above the
product's
flash point ( (see 'Fire Fighting Measures' in Section 5).).
- Thermal decomposition and burning may form toxic by-products.
- For large exposures or fire, wear personal protective equipment.
- Highly toxic to fish and aquatic organisms. Keep out of drains and water
courses.
POTENTIAL HEALTH EFFECTS: Effects from overexposure result from swallowing or
coming into contact with the skin or eyes. Symptoms of overexposure include
increased hypersensitivity to touch and sound, tremors and convulsions.
Contact with permethrin may produce skin sensations such as numbing, burning
or tingling. These skin sensations are reversible and usually subside within
12 hours.
MEDICAL CONDITIONS AGGRAVATED: None presently known.
4. FIRST AID MEASURES
EYES: Flush with water for at least 15 minutes. If irritation occurs and
persists, obtain medical attention.
SKIN: Wash with plenty of soap and water. Get medical attention if
irritation occurs and persists.
INGESTION: Rinse mouth with water. Dilute by giving 1 or 2 glasses of water.
Do not induce vomiting. Never give anything by mouth to an unconscious
person. See a medical doctor immediately.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort
occurs and persists, obtain medical attention.
NOTES TO MEDICAL DOCTOR: This product has low oral, dermal and inhalation
toxicity. It is minimally irritating to the eyes and slightly irritating to
the skin. The low oral toxicity of the product compared to the risk of
pneumonitis from aspiration of stoddard solvents suggests that vomiting
should not be induced. Consideration should be given to gastric lavage with
an endotracheal tube in place. Activated charcoal and a cathartic are
recommended and nervous stimulation should be controlled with a sedative,
e.g., barbiturates. Treatment is otherwise controlled removal of exposure
followed by symptomatic and supportive care. Reversible skin sensations
(paresthesia) may occur and ordinary skin salves have been found useful in
reducing discomfort. Treatment is otherwise controlled removal of exposure
followed by symptomatic and supportive care.
5. FIRE FIGHTING MEASURES
FLASH POINT AND METHOD: 47 deg C (118 deg F)
EXTINGUISHING MEDIA: Foam, CO2 or dry chemical. Soft stream water fog only
if necessary. Contain all runoff.
EXPLOSION HAZARDS: Moderately combustible. When heated above the flash
point, this material releases vapors which, when mixed with air, can burn or
be explosive.
FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full
protective clothing and self-contained breathing apparatus. Do not breathe
smoke, gases or vapors generated.
HAZARDOUS DECOMPOSITION PRODUCTS: Chlorine, hydrogen chloride, carbon
dioxide, carbon monoxide, and aldehydes.
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Isolate and post spill area. Wear protective clothing and
personal protective equipment as prescribed in Section 8, "Exposure
Controls/Personal Protection". Keep unprotected persons and animals out of
the area.
Keep material out of lakes, streams, ponds and sewer drains. Dike to confine
spill and absorb with a non-combustible absorbent such as clay, sand or
soil. Vacuum, shovel or pump waste into a drum and label contents for
disposal.
To clean and neutralize spill area, tools and equipment, wash with a
suitable solution (i.e., bleach or caustic/soda ash and either ethylene
glycol or an appropriate alcohol, i.e., methanol, ethanol or isopropanol).
Follow this by washing with a strong soap and water solution. Absorb as
above, any excess liquid and add to the drums of waste already collected.
Repeat if necessary. Dispose of drummed waste according to the method
outlined in Section 13, "Disposal Considerations".
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Store in a cool, dry, well-ventilated place. Do not use
or store near heat, open flame or hot surfaces. Store in original containers
only. Store at temperatures above 40 deg F (5 deg C). If crystals form, warm
to room temperature 70 deg F (21 deg C) by room heating only for 24-48
hours, and shake occasionally until crystals dissolve and product appears
uniform. Do not use external source of heat for warming container.
Keep out of reach of children and animals. Do not contaminate other
pesticides, fertilizers, water, food or feed by storage or disposal.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Use local exhaust at all process locations where vapor
or mist may be emitted. Ventilate all transport vehicles prior to unloading.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: For splash, mist or spray exposure, wear chemical protective
goggles or a face shield.
RESPIRATORY: For splash, mist or spray exposure wear, as a minimum, a
properly fitted half-face or full-face air-purifying respirator which is
approved for pesticides (U.S. NIOSH/MSHA, EU CEN or comparable certification
organization). Respirator use and selection must be based on airborne
concentrations.
PROTECTIVE CLOTHING: Depending upon concentrations encountered, wear
coveralls or long-sleeved uniform and head covering. For larger exposures as
in the case of spills, wear full body cover barrier suit, such as a PVC
suit. Leather items - such as shoes, belts and watchbands - that become
contaminated should be removed and destroyed. Launder all work clothing
before reuse (separately from household laundry).
WORK HYGIENIC PRACTICES: Clean water should be available for washing in case
of eye or skin contamination. Wash skin prior to eating, drinking or using
tobacco. Shower at the end of the workday.
GLOVES:
Wear chemical protective gloves made of materials such as nitrile, neoprene
or Viton(r) brand. Thoroughly wash the outside of gloves with soap and water
prior to removal. Inspect regularly for leaks.
COMMENTS: Personal protective recommendations for mixing or applying this
product are prescribed on the product label. Information stated above provides
useful, additional guidance for individuals whose use or handling of this
product is not guided by the product label.
9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR: Faint, mild petroleum
APPEARANCE: Amber liquid
pH: 5.3 - 5.8 @ 20 deg C (5% in water)
SOLUBILITY IN WATER: Emulsifies
SPECIFIC GRAVITY: 1.047 @ 20 deg C (water = 1)
MOLECULAR WEIGHT: 391.3 (permethrin)
WEIGHT PER VOLUME: 8.72 lb/gal. (1047 g/L)
10. STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Excessive heat and fire.
STABILITY: Stable
POLYMERIZATION: Will not occur
11. TOXICOLOGICAL INFORMATION
DERMAL LD50: >2000 mg/kg (rabbit)
ORAL LD50: 998 mg/kg (rat)
INHALATION LC50: >4.3 mg/L/4 hr (rat)
ACUTE EFFECTS FROM OVEREXPOSURE: This product has low oral, dermal and
inhalation toxicity. It is minimally irritating to the eyes and slightly
irritating to the skin. Experience to date indicates that contact with
permethrin has rarely produced skin sensations such as numbing, burning or
tingling. These skin sensations are reversible and usually subside within 12
hours. Large toxic doses, of the formulated product, administered to
laboratory animals have produced central nervous system effects with
symptoms that include hypersensitivity to touch and sound, tremors, and
clonic convulsions. Overexposure to animals via inhalation has also produced
symptoms such as squinting eyes, irregular and rattling breathing and
ataxia. Inhalation of stoddard solvent vapors may cause dizziness,
disturbances in vision, drowsiness, respiratory irritation, and eye, skin
and mucous membrane irritation. Vomiting after ingestion of this product may
cause aspiration of stoddard solvents into the lungs which may result in
fatal pulmonary edema.
CHRONIC EFFECTS FROM OVEREXPOSURE: No data available for the formulation. In
studies with laboratory animals, permethrin did not cause reproductive
toxicity or teratogenicity. Analysis of chronic feeding studies in both mice
and rats with permethrin resulted in the conclusion that permethrin's
potential for induction of oncogenicity in experimental animals is low and
that the likelihood of oncogenic effects in humans is nonexistent or
extremely low. Long term feeding studies in animals resulted in increased
liver and kidney weights, induction of the liver microsomal drug
metabolizing enzyme system, and histopathological changes in the lungs and
liver. An overall absence of genotoxicity has been demonstrated in
mutagenicity testing with permethrin. Chronic exposure to stoddard solvents
may cause headaches, dizziness, loss of sensations or feelings, and liver
and kidney damage.
CARCINOGENICITY:
IARC: Not listed
NTP: Not listed
OSHA: Not listed
OTHER: (ACGIH) Not listed
12. ECOLOGICAL INFORMATION
Unless otherwise indicated, the data presented below are for the active
ingredient.
ENVIRONMENTAL DATA: In soil, permethrin is stable over a wide range of pH
values. When applied at agricultural use rates, permethrin has a moderate
rate of degradation in soil. At termiticidal use rates, permethrin degrades
at a slower rate which is governed by soil characteristics. Due to its high
affinity for organic matter (Koc = 86,000), there is little potential for
movement in soil or entry into ground water. Permethrin has a Log Pow of
6.1, but a low potential to bioconcentrate (BCF = 500) due to the ease with
which it is metabolized.
ECOTOXICOLOGICAL INFORMATION: Permethrin is highly toxic to fish (LC50 = 0.5
ug/L to 315 ug/L) and aquatic arthropods (LC50 = 0.02 ug/L to 7.6 ug/L).
Marine species are often more sensitive than the freshwater species.
Bacteria, algae, mollusks and amphibians are much more tolerant of
permethrin than the fish and arthropods. Care should be taken to avoid
contamination of the aquatic environment. Permethrin is slightly toxic to
birds and oral LD50 values are greater than 3600 mg/kg. Longer dietary
studies showed that concentrations of up to 500 ppm in the diet had no
effect on bird reproduction.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Open dumping or burning of this material or its packaging
is prohibited. If spilled material cannot be disposed of by use according to
label instructions, an acceptable method of disposal is to incinerate in
accordance with local, state and national environmental laws, rules,
standards and regulations. However, because acceptable methods of disposal
may vary by location, and regulatory requirements may change, the
appropriate agencies should be contacted prior to disposal.
EMPTY CONTAINER: Non-returnable containers which held this material should
be cleaned, prior to disposal, by triple rinsing. Containers which held this
material may be cleaned by being triple-rinsed, and recycled, with the
rinsate being incinerated. Do not cut or weld metal containers. Vapors that
form may create an explosion hazard.
14. TRANSPORT INFORMATION
U.S. DOT (DEPARTMENT OF TRANSPORTATION)
REPORTABLE QUANTITY (RQ): None
U.S. SURFACE FREIGHT CLASS: Insecticides, NOI, other than Poison. NMFC Item
102120.
MARINE POLLUTANT #1: permethrin (Severe Marine Pollutant)
OTHER SHIPPING INFORMATION:
For highway and railroad shipment in the U.S.A. :
Insecticides, NOI, other than Poison.
For air and water shipment, and also road and rail other than in the U.S.A.
:
Flammable liquids, n.o.s. (contains stoddard solvent), 3, III, UN1993, NAERG
Guide 128
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311 HAZARD CATEGORIES (40 CFR 370): Immediate, Delayed, Fire
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370): The threshold planning
quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs.
This product contains the following ingredients with a TPQ of less than
10,000 lbs.: None
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372): This product contains the
following ingredients subject to Section 313 reporting requirements:
(permethrin)
SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): Not
listed
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT)
CERCLA REGULATORY (40 CFR 302.4): Not listed
COMMENTS: Australian Hazard Code : 3XE
U.S. EPA Signal Word : CAUTION
16. OTHER INFORMATION
Viton - E.I. du Pont de Nemours & Co. Trademark;
Dragnet and FMC Logo - FMC Trademarks
For emergency assistance involving chemicals,
call CHEMTREC - (800)
424-9300
Vopak USA
6100 Carillon Point, Kirkland WA 98033 - (425)
889-3400
Vopak USA expressly disclaims all express or implied warranties of
merchantability and fitness for a particular purpose, with respect to the
product or information provided herein, and shall under no circumstances be
liable for incidental or consequential damages.
All information appearing
herien is based upon data obtained from the manufacturer and/or recognized
technical sources. While the information is believed to be accurate, Vopak USA
makes no representations as to its accuracy or suffiency. Conditions of use are
beyond Vopak USA's control and therefore users are responsible to verify this
data under their own operating conditions to determine whether the product is
suitable for their particular purposes and they assume all risks of their use,
handling, and disposal of the product, or from the publication or use of, or
reliance upon, information contained herein. This information relates only to
the product designated herein, and does not relate to its use in combination
with any other material or in any other process.
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